Flame-retardant thermoset composition, method, and article

ABSTRACT

A curable composition includes a functionalized poly(arylene ether) resin, an acryloyl monomer, and a phosphorus flame retardant. The composition exhibits an improved balance of properties such as toughness, flame retardance, heat-resistance, and moisture resistance. It is useful, for example, as an encapsulant for semiconductor products.

CROSS REFERENCE TO RELATED APPLICATIONS

This application is a continuation-in-part of U.S. application Ser. No.10/678,471 filed Oct. 3, 2003.

BACKGROUND OF THE INVENTION

Curable compositions are often used to encapsulate electroniccomponents. These encapsulating materials must be self-extinguishing inthe case of ignition. Commercially available compositions forencapsulation typically employ a combination of halogenated aromaticcompounds and antimony oxides to achieve flame retardance. However, thehalogenated aromatic compounds interfere with the recycling ofelectronic devices, and concerns have been raised about health effectsassociated with antimony oxides. There is therefore a need forflame-retardant encapsulant compositions that reduce or eliminatehalogenated aromatic compounds and antimony oxides while maintaining orimproving the balance of toughness, heat resistance, and moistureresistance.

BRIEF DESCRIPTION OF THE INVENTION

One embodiment is a curable composition, comprising: a functionalizedpoly(arylene ether) resin; an acryloyl monomer; and a phosphorus flameretardant having the formula

wherein M^(d+) is a metal ion or an onium ion; d is 1, 2, 3, or 4according to the identity of M and its oxidation state; each occurrenceof R²³ and R²⁴ is independently C₁-C₁₈ hydrocarbyl; and each occurrenceof m and n is 0 or 1.

Other embodiments, including filled curable compositions, curedcompositions, and articles comprising the cured compositions, aredescribed in detail below.

DETAILED DESCRIPTION OF THE INVENTION

The present inventors have found that excellent flame retardance, heatresistance, moisture resistance, and toughness are exhibited by a curedcomposition comprising the cured product of: a functionalizedpoly(arylene ether) resin; an acryloyl monomer; and a phosphorus flameretardant having the formula

wherein M^(d+) is a metal ion or an onium ion; d is 1, 2, 3, or 4according to the identity of M and its oxidation state; each occurrenceof R²³ and R²⁴ is independently C₁-C₁₈ hydrocarbyl; and each occurrenceof m and n is 0 or 11.

The functionalized poly(arylene ether) may be a capped poly(aryleneether), a ring-functionalized poly(arylene ether), or an acid- oranhydride-functionalized poly(arylene ether). A capped poly(aryleneether) is defined herein as a poly(arylene ether) in which at least 50%,preferably at least 75%, more preferably at least 90%, yet morepreferably at least 95%, even more preferably at least 99%, of the freehydroxyl groups present in the corresponding uncapped poly(aryleneether) have been functionalized by reaction with a capping agent.

The capped poly(arylene ether) may be represented by the structureQ(J-K)_(y)wherein Q is the residuum of a monohydric, dihydric, or polyhydricphenol, preferably the residuum of a monohydric or dihydric phenol, morepreferably the residuum of a monohydric phenol; y is 1 to 100; Jcomprises repeating structural units having the formula

wherein m is 1 to about 200, preferably 2 to about 200, and R¹ and R³are each independently hydrogen, halogen, primary or secondary C₁-C₁₂alkyl, C₂-C₁₂ alkenyl, C₂-C₁₂ alkynyl, C₁-C₁₂ aminoalkyl, C₁-C₁₂hydroxyalkyl, phenyl, C₁-C₁₂ haloalkyl, C₁-C₁₂ hydrocarbyloxy, C₂-C₁₂halohydrocarbyloxy wherein at least two carbon atoms separate thehalogen and oxygen atoms, or the like; R² and R⁴ are each independentlyhalogen, primary or secondary C₁-C₁₂ alkyl, C₂-C₁₂ alkenyl, C₂-C₁₂alkynyl, C₁-C₁₂ aminoalkyl, C₁-C₁₂ hydroxyalkyl, phenyl, C₁-C₁₂haloalkyl, C₁-C₁₂ hydrocarbyloxy, C₂-C₁₂ halohydrocarbyloxy wherein atleast two carbon atoms separate the halogen and oxygen atoms, or thelike; and K is a capping group produced by reaction of a phenolichydroxyl group on the poly(arylene ether) with a capping agent. Theresulting capping group may be

or the like, wherein R⁵ is C₁-C₁₂ alkyl, or the like; R⁶-R⁸ are eachindependently hydrogen, C₁-C₁₈ hydrocarbyl, C₂-C₁₈hydrocarbyloxycarbonyl, nitrile, formyl, carboxylate, imidate,thiocarboxylate, or the like; R⁹-R¹³ are each independently hydrogen,halogen, C₁-C₁₂ alkyl, hydroxy, amino, or the like; and wherein Y is adivalent group such as

or the like, wherein R¹⁴ and R¹⁵ are each independently hydrogen, C₁-C₁₂alkyl, or the like. As used herein, “hydrocarbyl” refers to a residuethat contains only carbon and hydrogen. The residue may be aliphatic oraromatic, straight-chain, cyclic, bicyclic, branched, saturated, orunsaturated. The hydrocarbyl residue, when so stated however, maycontain heteroatoms over and above the carbon and hydrogen members ofthe substituent residue. Thus, when specifically noted as containingsuch heteroatoms, the hydrocarbyl residue may also contain carbonylgroups, amino groups, hydroxyl groups, or the like, or it may containheteroatoms within the backbone of the hydrocarbyl residue.

In one embodiment, Q is the residuum of a phenol, includingpolyfunctional phenols, and includes radicals of the structure

wherein R¹ and R³ are each independently hydrogen, halogen, primary orsecondary C₁-C₁₂ alkyl, C₂-C₁₂ alkenyl, C₂-C₁₂ alkynyl, C₁-C₁₂aminoalkyl, C₁-C₁₂ hydroxyalkyl, phenyl, C₁-C₁₂ haloalkyl, C₁-C₁₂aminoalkyl, C₁-C₁₂ hydrocarbyloxy, C₁-C₁₂ halohydrocarbyloxy wherein atleast two carbon atoms separate the halogen and oxygen atoms, or thelike; R² and R⁴ are each independently halogen, primary or secondaryC₁-C₁₂ alkyl, C₂-C₁₂ alkenyl, C₂-C₁₂ alkynyl, C₁-C₁₂ aminoalkyl, C₁-C₁₂hydroxyalkyl, phenyl, C₁-C₁₂ haloalkyl, C₁-C₁₂ aminoalkyl, C₁-C₁₂hydrocarbyloxy, C₁-C₁₂ halohydrocarbyloxy wherein at least two carbonatoms separate the halogen and oxygen atoms, or the like; X may behydrogen, C₁-C₁₈ hydrocarbyl, or C₁-C₁₈ hydrocarbyl containing asubstituent such as carboxylic acid, aldehyde, alcohol, amino radicals,or the like; X also may be sulfur, sulfonyl, sulfuryl, oxygen, or othersuch bridging group having a valence of 2 or greater to result invarious bis- or higher polyphenols; n (i.e., the number of phenyleneether units bound to X) is 1 to about 100, preferably 1 to 3, and morepreferably 1 to 2. Q may be the residuum of a monohydric phenol, such as2,6-dimethylphenol, in which case n is 1. Q may also be the residuum ofa diphenol, such as 2,2′,6,6′-tetramethyl-4,4′-diphenol, in which case nis 2.

In one embodiment, the capped poly(arylene ether) is produced by cappinga poly(arylene ether) consisting essentially of the polymerizationproduct of at least one monohydric phenol having the structure

wherein R¹ and R³ are each independently hydrogen, halogen, primary orsecondary C₁-C₁₂ alkyl, C₂-C₁₂ alkenyl, C₂-C₁₂ alkynyl, C₁-C₁₂aminoalkyl, C₁-C₁₂ hydroxyalkyl, phenyl, C₁-C₁₂ haloalkyl, C₁-C₁₂aminoalkyl, C₁-C₁₂ hydrocarbyloxy, C₁-C₁₂ halohydrocarbyloxy wherein atleast two carbon atoms separate the halogen and oxygen atoms, or thelike; and R² and R⁴ are each independently halogen, primary or secondaryC₁-C₁₂ alkyl, C₂-C₁₂ alkenyl, C₂-C₁₂ alkynyl, C₁-C₁₂ aminoalkyl, C₁-C₁₂hydroxyalkyl, phenyl, C₁-C₁₂ haloalkyl, C₁-C₁₂ aminoalkyl, C₁-C₁₂hydrocarbyloxy, C₁-C₁₂ halohydrocarbyloxy wherein at least two carbonatoms separate the halogen and oxygen atoms, or the like. Suitablemonohydric phenols include those described in U.S. Pat. No. 3,306,875 toHay, and highly preferred monohydric phenols include 2,6-dimethylphenoland 2,3,6-trimethylphenol. The poly(arylene ether) may be a copolymer ofat least two monohydric phenols, such as 2,6-dimethylphenol and2,3,6-trimethylphenol.

In one embodiment, the capped poly(arylene ether) comprises at least onecapping group having the structure

wherein R⁶-R⁸ are each independently hydrogen, C₁-C₁₈ hydrocarbyl,C₂-C₁₈ hydrocarbyloxycarbonyl, nitrile, formyl, carboxylate, imidate,thiocarboxylate, or the like. Highly preferred capping groups includeacrylate (R⁶=R⁷=R⁸=hydrogen) and methacrylate (R⁶=methyl,R⁷=R⁸=hydrogen). It will be understood that the term “(meth)acrylate”means either acrylate or methacrylate.

In another embodiment, the capped poly(arylene ether) comprises at leastone capping group having the structure

wherein R⁵ is C₁-C₁₂ alkyl, preferably C₁-C₆ alkyl, more preferablymethyl, ethyl, or isopropyl. The advantageous properties of theinvention can be achieved even when the capped poly(arylene ether) lacksa polymerizable function such as a carbon-carbon double bond.

In yet another embodiment, the capped poly(arylene ether) comprises atleast one capping group having the structure

wherein R⁹-R¹³ are each independently hydrogen, halogen, C₁-C₁₂ alkyl,hydroxy, amino, or the like. Preferred capping groups of this typeinclude salicylate (R⁹=hydroxy, R¹⁰-R¹³=hydrogen).

In still another embodiment, the capped poly(arylene ether) comprises atleast one capping group having the structure

wherein A is a saturated or unsaturated C₂-C₁₂ divalent hydrocarbongroup such as, for example, ethylene, 1,2-propylene, 1,3-propylene,2-methyl-1,3-propylene, 2,2-dimethyl-1,3-propylene, 1,2-butylene,1,3-butylene, 1,4-butylene, 2-methyl-1,4-butylene,2,2-dimethyl-1,4-butylene, 2,3-dimethyl-1,4-butylene, vinylene(—CH═CH—), 1,2-phenylene, and the like. These capped poly(arylene ether)resins may conveniently be prepared, for example, by reaction of anuncapped poly(arylene ether) with a cyclic anhydride capping agent. Suchcyclic anhydride capping agents include, for example, maleic anhydride,succinic anhydride, glutaric anhydride, adipic anhydride, phthalicanhydride, and the like.

There is no particular limitation on the method by which the cappedpoly(arylene ether) is prepared. The capped poly(arylene ether) may beformed by the reaction of an uncapped poly(arylene ether) with a cappingagent. Capping agents include compounds known in the literature to reactwith phenolic groups. Such compounds include both monomers and polymerscontaining, for example, anhydride, acid chloride, epoxy, carbonate,ester, isocyanate, cyanate ester, or alkyl halide radicals. Cappingagents are not limited to organic compounds as, for example, phosphorusand sulfur based capping agents also are included. Examples of cappingagents include, for example, acetic anhydride, succinic anhydride,maleic anhydride, salicylic anhydride, polyesters comprising salicylateunits, homopolyesters of salicylic acid, acrylic anhydride, methacrylicanhydride, glycidyl acrylate, glycidyl methacrylate, acetyl chloride,benzoyl chloride, diphenyl carbonates such asdi(4-nitrophenyl)carbonate, acryloyl esters, methacryloyl esters, acetylesters, phenylisocyanate, 3-isopropenyl-α,α-dimethylphenylisocyanate,cyanatobenzene, 2,2-bis(4-cyanatophenyl)propane,3-(α-chloromethyl)styrene, 4-(α-chloromethyl)styrene, allyl bromide, andthe like, and substituted derivatives thereof, and mixtures thereof.These and other methods of forming capped poly(arylene ether)s aredescribed, for example, in U.S. Pat. Nos. 3,375,228 to Holoch et al.;4,148,843 to Goossens; 4,562,243, 4,663,402, 4,665,137, and 5,091,480 toPercec et al.; 5,071,922, 5,079,268, 5,304,600, and 5,310,820 toNelissen et al.; 5,338,796 to Vianello et al.; U.S. Patent ApplicationPublication No. 2001/0053820 A1 to Yeager et al.; and European PatentNo. 261,574 B1 to Peters et al.

In a preferred embodiment, the curable composition further comprises analkenyl aromatic monomer, and the capped poly(arylene ether) is beprepared by reaction of an uncapped poly(arylene ether) with ananhydride in the alkenyl aromatic monomer as solvent. This approach hasthe advantage of generating the capped poly(arylene ether) in a formthat can be immediately blended with other components to form a curablecomposition. Using this method, no isolation of the capped poly(aryleneether) or removal of unwanted solvents or reagents is required.

A capping catalyst may be employed in the reaction of an uncappedpoly(arylene ether) with an anhydride. Examples of such compoundsinclude those known to the art that are capable of catalyzingcondensation of phenols with the capping agents described above. Usefulmaterials include, but are not limited to, basic compounds including,for example, basic compound hydroxide salts such as sodium hydroxide,potassium hydroxide, tetraalkylammonium hydroxides, and the like;tertiary alkylamines such as tributyl amine, triethylamine,dimethylbenzylamine, dimethylbutylamine and the like; tertiary mixedalkyl-arylamines and substituted derivatives thereof such asN,N-dimethylaniline; heterocyclic amines such as imidazoles, pyridines,and substituted derivatives thereof such as 2-methylimidazole,2-vinylimidazole, 4-(dimethylamino)pyridine, 4-(1-pyrrolino)pyridine,4-(1-piperidino)pyridine, 2-vinylpyridine, 3-vinylpyridine,4-vinylpyridine, and the like. Also useful are organometallic salts suchas, for example, tin and zinc salts known to catalyze the condensationof, for example, isocyanates or cyanate esters with phenols. Theorganometallic salts useful in this regard are known to the art innumerous publications and patents well known to those skilled in thisart.

The functionalized poly(arylene ether) may be a ring-functionalizedpoly(arylene ether). In one embodiment, the ring-functionalizedpoly(arylene ether) is a poly(arylene ether) comprising repeatingstructural units of the formula

wherein each L¹-L⁴ is independently hydrogen, a C₁-C₁₂ alkyl group, analkenyl group, or an alkynyl group; wherein the alkenyl group isrepresented by

wherein L⁵-L⁷ are independently hydrogen or methyl, and a is an integerfrom 0 to 4; wherein the alkynyl group is represented by

wherein L⁸ is hydrogen, methyl, or ethyl, and b is an integer from 0 to4; and wherein about 0.02 mole percent to about 25 mole percent of thetotal L¹-L⁴ substituents in the ring-functionalized poly(arylene ether)are alkenyl and/or alkynyl groups. Within this range, it may bepreferred to have at least about 0.1 mole percent, more preferably atleast about 0.5 mole percent, alkenyl and/or alkynyl groups. Also withinthis range, it may be preferred to have up to about 15 mole percent,more preferably up to about 10 mole percent, alkenyl and/or alkynylgroups.

The ring-functionalized poly(arylene ether) may be prepared according toknown methods. For example, an unfunctionalized poly(arylene ether) suchas poly(2,6-dimethyl-1,4-phenylene ether) may be metallized with areagent such as n-butyl lithium and subsequently reacted with an alkenylhalide such as allyl bromide and/or an alkynyl halide such as propargylbromide. This and other methods for preparation of ring-functionalizedpoly(arylene ether) resins are described, for example, in U.S. Pat. No.4,923,932 to Katayose et al.

In another embodiment, the functionalized poly(arylene ether) is theproduct of the melt reaction of a poly(arylene ether) and anα,β-unsaturated carbonyl compound or a β-hydroxy carbonyl compound toproduce an acid- or anhydride-functionalized poly(arylene ether). Insome embodiments both acid and anhydride functionality may be present.Examples of α,β-unsaturated carbonyl compounds include, for example,fumaric acid, maleic acid, maleic anhydride, itaconic acid, itaconicanhydride, citraconic acid, citraconic anhydride, as well as variousderivatives of the foregoing and similar compounds. Examples ofβ-hydroxy carbonyl compounds include, for example, citric acid, malicacid, and the like. Such functionalization is typically carried out bymelt mixing the poly(arylene ether) with the desired carbonyl compoundat a temperature of about 190 to about 290° C.

There is no particular limitation on the molecular weight or intrinsicviscosity of the functionalized poly(arylene ether). In one embodiment,the composition may comprise a functionalized poly(arylene ether) havinga number average molecular weight of about 1,000 to about 25,000 atomicmass units (AMU). Within this range, it may be preferable to use afunctionalized poly(arylene ether) having a number average molecularweight of at least about 2,000 AMU, more preferably at least about 4,000AMU. In another embodiment, the composition may comprise afunctionalized poly(arylene ether) having an intrinsic viscosity ofabout 0.05 to about 0.6 deciliters per gram (dL/g) as measured inchloroform at 25° C. Within this range, the functionalized poly(aryleneether) intrinsic viscosity may preferably be at least about 0.08 dL/g,more preferably at least about 0.1 dL/g. Also within this range, thefunctionalized poly(arylene ether) intrinsic viscosity may preferably beup to about 0.5 dL/g, still more preferably up to about 0.4 dL/g.Generally, the intrinsic viscosity of a functionalized poly(aryleneether) will vary insignificantly from the intrinsic viscosity of thecorresponding unfunctionalized poly(arylene ether). Specifically, theintrinsic viscosity of a functionalized poly(arylene ether) willgenerally be within 10% of that of the unfunctionalized poly(aryleneether). It is expressly contemplated to employ blends of at least twofunctionalized poly(arylene ether)s having different molecular weightsand intrinsic viscosities. The composition may comprise a blend of atleast two functionalized poly(arylene ethers). Such blends may beprepared from individually prepared and isolated functionalizedpoly(arylene ethers). Alternatively, such blends may be prepared byreacting a single poly(arylene ether) with at least two functionalizingagents. For example, a poly(arylene ether) may be reacted with twocapping agents, or a poly(arylene ether) may be metallized and reactedwith two unsaturated alkylating agents. In another alternative, amixture of at least two poly(arylene ether) resins having differentmonomer compositions and/or molecular weights may be reacted with asingle functionalizing agent. The composition may, optionally, comprisea blend of a functionalized poly(arylene ether) resin and anunfunctionalized poly(arylene ether) resin, and these two componentsmay, optionally, have different intrinsic viscosities.

The curable composition may comprise about 5 to about 90 parts by weightof the functionalized poly(arylene ether) per 100 parts by weight totalof the functionalized poly(arylene ether) and the acryloyl monomer.Within this range, the amount of the functionalized poly(arylene ether)resin may preferably be at least about 10 parts by weight, morepreferably at least about 15 parts by weight. Also within this range,the amount of the functionalized poly(arylene ether) resin maypreferably be up about 80 parts by weight, more preferably up to about60 parts by weight, still more preferably up to about 50 parts byweight.

The composition comprises an acryloyl monomer. In one embodiment, theacryloyl monomer comprises at least one acryloyl moiety having thestructure

wherein R¹⁸ and R¹⁹ are each independently selected from the groupconsisting of hydrogen and C₁-C₁₂ alkyl, and wherein R¹⁸ and R¹⁹ may bedisposed either cis or trans about the carbon-carbon double bond.Examples of acryloyl monomers having the above structure include, forexample, unsaturated polyester resins obtained by reaction of at leastone polyhydric alcohol with at least one polybasic acid comprising anunsaturated polybasic acid. Suitable unsaturated polyester resins aredescribed, for example, in U.S. Pat. No. 6,521,703 to Zarnoch et al.

In another embodiment, the acryloyl monomer comprises at least oneacryloyl moiety having the structure

wherein R²⁰-R²² are each independently selected from the groupconsisting of hydrogen, C₁-C₁₂ hydrocarbyl, C₂-C₁₈hydrocarbyloxycarbonyl, nitrile, formyl, carboxylate, imidate, andthiocarboxylate. In one embodiment, the acryloyl monomer comprises atleast two acryloyl moieties. In another embodiment, the acryloyl monomercomprises at least three acryloyl moieties. Suitable acryloyl monomersinclude, for example, trimethylolpropane tri(meth)acrylate,1,6-hexanediol di(meth)acrylate, neopentyl glycol di(meth)acrylate,ethylene glycol di(meth)acrylate, propylene glycol di(meth)acrylate,cyclohexanedimethanol di(meth)acrylate, butanediol di(meth)acrylate,diethylene glycol di(meth)acrylate, triethylene glycol di(meth)acrylate,isobornyl (meth)acrylate, methyl (meth)acrylate, ethoxylated (2)bisphenol A di(meth)acrylate (it will be understood that the numberfollowing the ethoxylated term refers to the average number of ethoxygroups in the ethoxylate chains attached to each oxygen of bisphenol A),4-biphenyl (meth)acrylate, 4,4′-biphenol di(meth)acrylate, and the like,and mixtures comprising at least one of the foregoing acryloyl monomers.

The composition may comprise about 10 to about 95 parts acryloyl monomerper 100 parts by weight total of the functionalized poly(arylene ether)and the acryloyl monomer. Within this range, the amount of the acryloylmonomer may preferably be at least about 20 parts by weight, morepreferably at least about 30 parts by weight, still more preferably atleast about 40 parts by weight. Also within this range, the amount ofthe acryloyl monomer may preferably be up to about 90 parts by weight,more preferably up to about 85 parts by weight, still more preferably upto about 80 parts by weight.

The composition comprises a phosphorus flame retardant having theformula

wherein M^(d+) is a metal ion or an onium ion; d is 1, 2, 3, or 4according to the identity of M and its oxidation state; each occurrenceof R²³ and R²⁴ is independently C₁-C₁₈ hydrocarbyl; and each occurrenceof m and n is 0 or 1. When M^(d+) is a metal ion, M may be, for exampleMg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, or K. Inparticular, M^(d+) may be, for example, Mg²⁺, Ca²⁺, Al³⁺, Sb³⁺, Sn⁴⁺,Ge⁴⁺, Ti⁴⁺, Zn²⁺, Fe²⁺, Fe³⁺, Ce³⁺, Ce⁴⁺, Bi³⁺, Sr²⁺, Mn²⁺, Mn³⁺, Mn⁴⁺,Li⁺, Na⁺ or K⁺ In one embodiment, M^(d+) is Al³⁺ or Zn²⁺. The ion M^(d+)may also be an onium cation, such as an ammonium cation (includingmono-, di-, tri-, and tetra-(C₁-C₁₂)-hydrocarbyl ammonium cations), aphosphonium cation (including mono-, di-, tri-, andtetra-(C₁-C₁₂)-hydrocarbyl phosphonium cations), or a sulfonium cation(including mono-, di-, and tri-(C₁-C₁₂)-hydrocarbyl sulfonium cations).In another embodiment, M^(d+) is Al³⁺. In one embodiment, eachoccurrence of R²³ and R²⁴ is independently C₁-C₆ alkyl. In anotherembodiment, each occurrence of R²³ and R²⁴ is methyl or ethyl. In oneembodiment, each occurrence of m and n is zero. Suitable phosphorusflame retardants include, for example, metal salts ofdimethylphosphinate, diethylphosphinate, di-n-propylphosphinate,di-n-butylphosphinate, di-n-hexylphosphinate, dicyclohexylphosphinate,di-2-ethylhexylphosphinate, diphenylphosphinate, di-o-tolylphosphinate,dimethylphosphonate, diethylphosphonate, di-n-propylphosphonate,di-n-butylphosphonate, di-n-hexylphosphonate, dicyclohexylphosphonate,di-2-ethylhexylphoshate, diphenylphosphonate, di-o-tolylphosphonate,dimethylphosphate, diethylphosphate, di-n-propylphosphate,di-n-butylphosphate, di-n-hexylphosphate, dicyclohexylphosphate,di-2-ethylhexylphoshate, diphenylphosphate, di-o-tolylphosphate, and thelike, and mixtures thereof. A preferred phosphorus flame retardant isaluminum tris(diethylphosphinate). Preparation of phosphorus flameretardants is described, for example, in U.S. Pat. Nos. 6,255,371 and6,547,992 to Schlosser et al., and 6,355,832 and 6,534,673 to Weferlinget al.

The composition may comprise about 0.1 to about 50 parts by weight ofthe phosphorus flame retardant per 100 parts by weight total of thefunctionalized poly(arylene ether) and the acryloyl monomer. Within thisrange, the phosphorus flame retardant amount may preferably be at leastabout 1 part by weight, more preferably at least about 4 parts byweight, still more preferably at least about 8 parts by weight. Alsowithin this range, the phosphorus flame retardant amount may preferablybe up to about 40 parts by weight, more preferably up to about 30 partsby weight, still more preferably up to about 20 parts by weight.

The composition may, optionally, comprise additional flame retardants.In one embodiment, the composition comprises an aromaticbisphosphoramidate flame retardant of the formula

wherein A is a monocyclic aromatic radical and D¹ is a C₁₋₄ primary orsecondary alkyl radical or both D¹ radicals taken together are ethylene.The monocyclic aromatic radical A may be, for example, an aromatichydrocarbon radical or substituted aromatic hydrocarbon radical whereinthe substituent(s) may be, for example, alkyl, alkoxy, nitro orcarbalkoxy groups. The preferred aromatic radicals are phenyl,2,6-dialkylphenyl (especially 2,6-xylyl), and 2,3,6-trialkylphenyl or2,4,6-trialkylphenyl (especially 2,3,6-trimethylphenyl or2,4,6-trimethylphenyl). Each D¹ radical is primary or secondary C₁₋₄alkyl, preferably methyl, or both of said radicals taken together areethylene. Bisphosphoramidates of the desired molecular structure may beprepared by the reaction of a corresponding secondary diamine such aspiperazine or N,N′-dimethylethylenediamine with a diaryl chlorophosphateof the formula (AO)₂POCl in the presence of a tertiary amine. Thismethod of preparation is described in Talley, J. Chem. Eng. Data, volume33, pages 221-222 (1988). When present, the aromatic bisphosphoramidatemay be used in an amount of about 0.1 to about 30 parts by weight per100 parts by weight total of the functionalized poly(arylene ether) andthe acryloyl monomer.

In another embodiment, the composition optionally comprises an aromaticpolyphosphate flame retardant having the formula

wherein each occurrence of R⁶-R⁸ is independently selected from thegroup consisting of hydrogen, C₁-C₁₈ hydrocarbyl, C₂-C₁₂hydrocarbyloxycarbonyl, nitrile, formyl, carboxylate, imidate, andthiocarboxylate; r is 2 to about 20; and each occurrence of s is 0, 1,or 2, with the proviso that at least one occurrence of s is 1.Preferably, each occurrence of R⁶ is hydrogen or methyl, each occurrenceof R⁷ and R⁸ is hydrogen, r is 2 to about 10, and each occurrence of sis 1. The aromatic polyphosphate flame retardant may be prepared byreacting phenyl dichlorophosphate with an excess of the dihydroxybenzeneof interest in the presence of magnesium or aluminium chloride to givethe bis(hydroxyphenyl) phenyl phosphate; this material is then reactedwith the appropriate acryloyl chloride in the presence of an acidacceptor such as a tertiary amine to give the structure of interest.When present, the aromatic polyphosphate flame retardant may be used inan amount of about 0.1 to about 30 parts by weight per 100 parts byweight total of the functionalized poly(arylene ether) and the acryloylmonomer. The composition may, optionally, include additional flameretardants including, for example, antimony oxides (e.g., Sb₂O₅ andSb₂O₃), magnesium hydroxide, the diglycidyl ether of tetrabromobisphenolA, dibromostyrenes, and the like.

The composition may, optionally, comprise a nitrogen-containing flameretardant. Suitable nitrogen-containing flame retardants includetriazines, guanidines, cyanurates, isocyanurates, ammoniumpolyphosphates, and the like, and mixtures thereof. Suitable triazinesinclude those having the formula

wherein R^(25,) R^(26,) and R²⁷ are each independently C₁-C₁₂ alkyl,C₁-C₁₂ alkoxyl, C₆-C₁₂ aryl, amino, C₁-C₁₂ alkyl-substituted amino, orhydrogen. Preferred triazines include melamine (Chemical AbstractsService Registry No. 108-78-1), melam (3576-88-3), melem (1502-47-2),melon (32518-77-7), ammeline (645-92-1), ammelide (645-93-2),ureidomelamine (16439-79-5), acetoguanamine (542-02-9), benzoguanamine(91-76-9), and the like. Triazines further include salts and adducts ofthese compounds with boric acid, phosphoric acid. Examples includemelamine phosphate, melamine pyrophosphate, and melamine polyphosphate.Suitable guanidine compounds include guanidine, aminoguanidine, and thelike; and their salts and adducts with boric acid, carbonic acid,phosphoric acid, nitric acid, sulfuric acid, and the like; and mixturesthereof. Suitable cyanurate and isocyanurate compounds include the saltsand adducts of the triazine compounds with cyanuric acid and isocyanuricacid, such as melamine cyanurate and melamine isocyanurate. Thenitrogen-containing flame retardants are known in the art, as aremethods for their preparation, and many are commercially available.

In one embodiment, the nitrogen-containing flame retardant synergistcomprises a melamine polyphosphate represented by the formula

wherein g has an average value of about 3 to about 10,000, and the ratioof f to g is about 0.5:1 to about 1.7:1. Within this range, the averagevalue of g specifically may be at least about 5, more specifically atleast about 10. Also within this range, the average value of gspecifically may be up to about 1,000, more specifically up to about500. Within the above range, the ratio of f to g specifically may be atleast about 0.7:1, more specifically at least about 0.9:1. Also withinthis range, the ratio of f to g specifically may be up to about 1.3:1,more specifically up to about 1.1:1. Melamine polyphosphates may beprepared by reacting polyphosphoric acid and melamine, as described inU.S. Pat. No. 6,025,419 to Kasowski et al., or by heating melaminepyrophosphate under nitrogen at 290° C. to constant weight, as describedin International Patent Application No. WO 98/08898 A1 to Jacobson etal.

When present in the composition, the nitrogen-containing flame retardantmay be used in an amount of about 0.1 to about 30 parts by weight, basedon 100 parts by weight total of the functionalized poly(arylene ether)and the acryloyl monomer. Within this range, the nitrogen-containingflame retardant synergist amount specifically may be at least about 0.5parts by weight, even more specifically at least about 0.8 parts byweight. Also within this range, the nitrogen-containing flame retardantsynergist amount specifically may be up to about 25 parts by weight,more preferably up to about 20 parts by weight.

In one embodiment, the composition comprises the phosphorus flameretardant and the nitrogen-containing flame retardant. In thisembodiment, the weight ratio of the phosphorus flame retardant to thenitrogen-containing flame retardant may be about 1:1 to about 100:1.Within this range, the ratio specifically may be at least about 2:1,more specifically at least about 5:1. Also within this range, the ratiomay specifically be up to about 50:1, more specifically up to about25:1. Any of the above flame retardants may, optionally, be used incombination with conventional flame retardants for polyphenylene ethercompositions such as, for example, resorcinol bis(diphenyl phosphate),or bisphenol A bis(diphenyl phosphate).

The composition may, optionally, further comprise an alkenyl aromaticmonomer. The alkenyl aromatic monomer may have the formula

wherein each occurrence of R¹⁶ is independently hydrogen or C₁-C₁₈hydrocarbyl; each occurrence of R¹⁷ is independently halogen, C₁-C₁₂alkyl, C₁-C₁₂ alkoxyl, or C₆-C₁₈ aryl; p is 1 to 4; and q is 0 to 5.Unspecified positions on the aromatic ring are substituted with hydrogenatoms. Suitable alkenyl aromatic monomers include, for example, styrene,α-methylstyrene, 2-methylstyrene, 3-methylstyrene, 4-methylstyrene,2-t-butylstyrene, 3-t-butylstyrene, 4-t-butylstyrene,1,3-divinylbenzene, 1,4-divinylbenzene, 1,3-diisopropenylbenzene,1,4-diisopropenylbenzene, styrenes having from 1 to 5 halogensubstituents on the aromatic ring, and the like, and combinationsthereof. When the composition comprises an alkenyl aromatic monomer, itmay be present at about 10 to about 500 parts by weight alkenyl aromaticmonomer per 100 parts by weight total of the functionalized poly(aryleneether) and the acryloyl monomer. Within this range, it may be preferableto use an alkenyl aromatic monomer amount of at least about 25 parts byweight, more preferably at least about 50 parts by weight. Also withinthis range, it may be preferable to use an alkenyl aromatic monomeramount of up to about 300 parts by weight, more preferably up to about100 parts by weight.

The composition may, optionally, further comprise an allylic monomer. Anallylic monomer is an organic compound comprising at least one,preferably at least two, more preferably at least three allyl(—CH₂—CH═CH₂) groups. Suitable allylic monomers include, for example,diallyl phthalate, diallyl isophthalate, triallyl mellitate, triallylmesate, triallyl benzenes, triallyl cyanurate, triallyl isocyanurate,mixtures thereof, partial polymerization products prepared therefrom,and the like. When the composition comprises an allylic monomer, it maybe present at about 10 to about 500 parts by weight allylic monomer per100 parts by weight total of the functionalized poly(arylene ether) andthe acryloyl monomer. Within this range, it may be preferable to use anallylic monomer amount of at least about 25 parts by weight, morepreferably at least about 50 parts by weight. Also within this range, itmay be preferable to use an allylic monomer amount of up to about 300parts by weight, more preferably up to about 100 parts by weight.

The curable composition may, optionally, further comprise a curingcatalyst to increase the curing rate of the unsaturated components.Curing catalysts, also referred to as initiators, are well known to theart and may be used to initiate the polymerization, cure or crosslinkany of numerous thermoplastics and thermosets including unsaturatedpolyester, vinyl ester and allylic thermosets. Non-limiting examples ofcuring catalysts are those described in U.S. Pat. Nos. 5,407,972 toSmith et al., and 5,218,030 to Katayose et al. The curing catalyst forthe unsaturated portion of the thermoset may include any compoundcapable of producing free radicals at elevated temperatures. Such curingcatalysts may include both peroxy and non-peroxy based radicalinitiators. Examples of useful peroxy initiators include, for example,benzoyl peroxide, dicumyl peroxide, methyl ethyl ketone peroxide, laurylperoxide, cyclohexanone peroxide, t-butyl hydroperoxide, t-butyl benzenehydroperoxide, t-butyl peroctoate,2,5-dimethylhexane-2,5-dihydroperoxide,2,5-dimethyl-2,5-di(t-butylperoxy)-hex-3-yne, di-t-butylperoxide,t-butylcumyl peroxide, α,α′-bis(t-butylperoxy-m-isopropyl)benzene,2,5-dimethyl-2,5-di(t-butylperoxy)hexane, di(t-butylperoxy)isophthalate, t-butylperoxybenzoate, 2,2-bis(t-butylperoxy)butane,2,2-bis(t-butylperoxy)octane, 2,5-dimethyl-2,5-di(benzoylperoxy)hexane,di(trimethylsilyl)peroxide, trimethylsilylphenyltriphenylsilyl peroxide,and the like, and mixtures comprising at least one of the foregoingcuring catalysts. Typical non-peroxy initiators include, for example,2,3-dimethyl-2,3-diphenylbutane,2,3-trimethylsilyloxy-2,3-diphenylbutane, and the like, and mixturescomprising at least one of the foregoing curing catalysts. The curingcatalyst for the unsaturated portion of the thermoset may furtherinclude any compound capable of initiating anionic polymerization of theunsaturated components. Such anionic polymerization catalysts include,for example, alkali metal amides, such as sodium amide (NaNH₂) andlithium diethyl amide (LiN(C₂H₅)₂); alkali metal and ammonium salts ofC₁-C₁₀ alkoxides; alkali metal and ammonium hydroxides; alkali metalcyanides; organometallic compounds such as the alkyl lithium compoundn-butyl lithium and the Grignard reagent phenyl magnesium bromide; andthe like; and combinations comprising at least one of the foregoinganionic polymerization catalysts.

In a preferred embodiment, the curing catalyst may compriset-butylperoxybenzoate or dicumyl peroxide. The curing catalyst maypromote curing at a temperature of about 0° C. to about 200° C.

When present, the curing catalyst may be used in an amount of about 0.1to about 10 parts by weight per 100 parts total of the functionalizedpoly(arylene ether) and the acryloyl monomer. Within this range, it maybe preferred to use a curing catalyst amount of at least about 0.5 partsby weight, more preferably at least about 1 part by weight. Also withinthis range, it may be preferred to use a curing catalyst amount of up toabout 5 parts by weight, more preferably up to about 3 parts by weight.

The curable composition may, optionally, further comprise a curingpromoter to decrease the gel time. Suitable curing promoters includetransition metal salts and complexes such as cobalt naphthanate; andorganic bases such as N,N-dimethylaniline (DMA) and N,N-diethylaniline(DEA). Preferably, cobalt naphthanate and DMA are used in combination.When present, the promoter may be used in an amount of about 0.05 toabout 3 parts, per 100 parts total of the functionalized poly(aryleneether) and the acryloyl monomer.

The composition may, optionally, further comprise a curing inhibitor,which functions to prevent premature curing of the composition. Suitablecuring inhibitors include, for example, diazoaminobenzene,phenylacetylene, sym-trinitrobenzene, p-benzoquinone, acetaldehyde,aniline condensates, N,N′-dibutyl-o-phenylenediamine,N-butyl-p-aminophenol, 2,4,6-triphenylphenoxyl, pyrogallol, catechol,hydroquinone, C₁-C₆-alkyl-substituted catechols, dialkylhydroquinone,2,4,6-dichloronitrophenol, halogen-ortho-nitrophenols,alkoxyhydroquinone, mono- and di- and polysulfides of phenols andcatechols, thiols and oximes and hydrazones of quinone, phenothiazine,dialkylhydroxylamines, and the like, and combinations comprising atleast one of the foregoing curing inhibitors. Preferred curinginhibitors include benzoquinone, hydroquinone, and tert-butylcatechol.When present, the curing inhibitor amount may be about 0.01 to about 10parts by weight, per 100 parts by weight total of the functionalizedpoly(arylene ether) resin and the acryloyl monomer. Within this range,the curing inhibitor amount may preferably be at least about 0.1 part byweight. Also within this range, the curing inhibitor amount maypreferably be up to about 2 parts by weight.

The composition may further comprise one or more fillers, includingparticulate fillers and fibrous fillers. Examples of such fillers wellknown to the art include those described in “Plastic Additives Handbook,4th Edition” R. Gachter and H. Muller (eds.), P. P. Klemchuck (assoc.ed.) Hanser Publishers, New York 1993, pages 901-948. A particulatefiller is herein defined as a filler having an average aspect ratio lessthan about 5:1. Non-limiting examples of fillers include silica powder,such as fused silica and crystalline silica; boron-nitride powder andboron-silicate powders for obtaining cured products having high thermalconductivity, low dielectric constant and low dielectric loss tangent;the above-mentioned powder as well as alumina, and magnesium oxide (ormagnesia) for high temperature conductivity; and fillers, such aswollastonite including surface-treated wollastonite, calcium sulfate (inits anhydrous, hemihydrated, dihydrated, or trihydrated forms), calciumcarbonate including chalk, limestone, marble and synthetic, precipitatedcalcium carbonates, generally in the form of a ground particulate whichoften comprises 98+% CaCO₃ with the remainder being other inorganicssuch as magnesium carbonate, iron oxide, and alumino-silicates;surface-treated calcium carbonates; talc, including fibrous, modular,needle shaped, and lamellar talc; glass spheres, both hollow and solid,and surface-treated glass spheres typically having coupling agents suchas silane coupling agents and/or containing a conductive coating; andkaolin, including hard, soft, calcined kaolin, and kaolin comprisingvarious coatings known to the art to facilitate the dispersion in andcompatibility with the thermoset resin; mica, including metallized micaand mica surface treated with aminosilanes or acryloylsilanes coatingsto impart good physical properties to compounded blends; feldspar andnepheline syenite; silicate spheres; flue dust; cenospheres; finite;aluminosilicate (atmospheres), including silanized and metallizedaluminosilicate; natural silica sand; quartz; quartzite; perlite;Tripoli; diatomaceous earth; synthetic silica, including those withvarious silane coatings, and the like.

Preferred particulate fillers include fused silica having an averageparticle size of about 1 to about 50 micrometers. A particularlypreferred particulate filler comprises a first fused silica having amedian particle size of about 0.03 micrometer to less than 1 micrometer,and a second fused silica having a median particle size of at least 1micrometer to about 30 micrometers. The preferred fused silicas haveessentially spherical particles, typically achieved by re-melting.Within the size range specified above, the first fused silica maypreferably have a median particle size of at least about 0.1 micrometer,preferably at least about 0.2 micrometer. Also within the size rangeabove, the first fused silica may preferably have a median particle sizeof up to about 0.9 micrometer, more preferably up to about 0.8micrometer. Within the size range specified above, the second fusedsilica may preferably have a median particle size of at least about 2micrometers, preferably at least about 4 micrometers. Also within thesize range above, the second fused silica may preferably have a medianparticle size of up to about 25 micrometers, more preferably up to about20 micrometers. In one embodiment, the composition comprises the firstfused silica and the second fused silica in a weight ratio of about70:30 to about 99:1, preferably about 80:20 to about 95:5.

Fibrous fillers include short inorganic fibers, including processedmineral fibers such as those derived from blends comprising at least oneof aluminum silicates, aluminum oxides, magnesium oxides, and calciumsulfate hemihydrate. Also included among fibrous fillers are singlecrystal fibers or “whiskers” including silicon carbide, alumina, boroncarbide, carbon, iron, nickel, copper. Also included among fibrousfillers are glass fibers, including textile glass fibers such as E, A,C, ECR, R, S, D, and NE glasses and quartz. Preferred fibrous fillersinclude glass fibers having a diameter of about 5 to about 25micrometers and a length before compounding of about 0.5 to about 4centimeters. Many other suitable fillers are described in U.S. PatentApplication Publication No. 2001/0053820 A1 to Yeager et al.

The formulation may also contain adhesion promoters to improve adhesionof the thermosetting resin to the filler or to an external coating orsubstrate. Also possible is treatment of the aforementioned inorganicfillers with adhesion promoter to improve adhesion. Adhesion promotersinclude chromium complexes, silanes, titanates, zirco-aluminates,propylene maleic anhydride copolymers, reactive cellulose esters and thelike. Chromium complexes include those sold by DuPont under thetradename VOLAN®. Silanes include molecules having the general structure(RO)_((4-n))SiY_(n) wherein n=1-3, R is an alkyl or aryl group and Y isa reactive functional group which can enable formation of a bond with apolymer molecule. Particularly useful examples of coupling agents arethose having the structure (RO)₃SiY. Typical examples include vinyltriethoxysilane, vinyl tris(2-methoxy)silane, phenyl trimethoxysilane,γ-methacryloxypropyltrimethoxy silane, γ-aminopropyltriethoxysilane,γ-glycidoxypropyltrimethoxysilane, γ-mercaptopropyltrimethoxysilane, andthe like. Silanes further include molecules lacking a reactivefunctional group, such as, for example, trimethoxyphenylsilane.Titanates include those developed by S. J. Monte et al. in Ann. Chem.Tech Conf. SPI (1980), Ann. Tech Conf. Reinforced Plastics and CompositeInst. SPI 1979, Section 16E, New Orleans; and S. J. Monte, Mod. PlasticsInt., volume 14, number 6 pg. 2 (1984). Zirco-aluminates include thosedescribed by L. B. Cohen in Plastics Engineering, volume 39, number 11,page 29 (1983). The adhesion promoter may be included in thethermosetting resin itself, or coated onto any of the fillers describedabove to improve adhesion between the filler and the thermosettingresin. For example such promoters may be used to coat a silicate fiberor filler to improve adhesion of the resin matrix.

When present, the particulate filler may be used in an amount of about 5to about 95 weight percent, based on the total weight of thecomposition. Within this range, it may be preferable to use aparticulate filler amount of at least about 20 weight percent, morepreferably at least about 40 weight percent. Also within this range, itmay be preferable to use a particulate filler amount of up to about 93weight percent, more preferably up to about 91 weight percent.

When present, the fibrous filler may be used in an amount of about 2 toabout 80 weight percent, based on the total weight of the composition.Within this range, it may be preferred to use a fibrous filler amount ofat least about 5 weight percent, more preferably at least about 10weight percent, yet more preferably at least about 15 weight percent.Also within this range, it may be preferred to use a fibrous filleramount of up to about 60 weight percent, more preferably up to about 40weight percent, still more preferably up to about 30 weight percent.

The aforementioned fillers may be added to the thermosetting resinwithout any treatment, or after surface treatment, generally with anadhesion promoter.

The curable composition may, optionally, further comprise one or moreadditives known in the art, such as, for example, dyes, pigments,colorants, antioxidants, heat stabilizers, light stabilizers,plasticizers, lubricants, flow modifiers, drip retardants, antiblockingagents, antistatic agents, flow-promoting agents, processing aids,substrate adhesion agents, mold release agents, toughening agents,low-profile additives, stress-relief additives, and the like, andcombinations thereof. Those skilled in the art may select suitableadditives and determine suitable amounts.

One embodiment is a curable composition, comprising: a(meth)acrylate-capped poly(2,6-dimethyl-1,4-phenylene ether) resin, a(meth)acrylate-capped poly(2,6-dimethyl-1,4-phenyleneether-co-2,3,6-trimethyl-1,4-phenylene ether) resin, or a mixturethereof; an acryloyl monomer selected from trimethylolpropanetri(meth)acrylate, hexanediol di(meth)acrylate, cyclohexanedimethanoldi(meth)acrylate, methacryloxypropyl trimethoxysilane, ethoxylated (2)bisphenol A di(meth)acrylate, or a mixture thereof; an aluminophosphorusflame retardant having the formula

wherein each occurrence of R²³ and R²⁴ is independently C₁-C₆ alkyl, andeach occurrence of m and n is 0; and fused silica.

Another embodiment is a curable composition, comprising: about 5 to abut40 parts by weight of a (meth)acrylate-cappedpoly(2,6-dimethyl-1,4-phenylene ether) resin, a (meth)acrylate-cappedpoly(2,6-dimethyl-1,4-phenylene ether-co-2,3,6-trimethyl-1,4-phenyleneether) resin, or a mixture thereof; about 60 to about 9 parts by weightof an acryloyl monomer selected from trimethylolpropanetri(meth)acrylate, hexanediol di(meth)acrylate, cyclohexanedimethanoldi(meth)acrylate, methacryloxypropyl trimethoxysilane, ethoxylated (2)bisphenol A di(meth)acrylate, or a mixture thereof; about 1 to about 50parts by weight of aluminum tris(diethylphosphinate); and about 100 toabout 2,000 parts by weight of fused silica; wherein all parts by weightare based on 100 parts by weight total for the (meth)acrylate-cappedpoly(arylene ether) resin and the acryloyl monomer.

Another embodiment is a method of preparing a curable composition,comprising: blending a functionalized poly(arylene ether) resin; anacryloyl monomer; and a phosphorus flame retardant having the formula

wherein M^(d+) is a metal ion or an onium ion; d is 1, 2, 3, or 4according to the identity of M and its oxidation state; each occurrenceof R²³ and R²⁴ is independently C₁-C₁₈ hydrocarbyl; and each occurrenceof m and n is 0 or 1, to form an intimate blend.

There is no particular limitation on the method by which the compositionis prepared. The composition may be prepared by forming an intimateblend comprising the functionalized poly(arylene ether), the acryloylmonomer, and the phosphorus flame retardant. When the compositioncomprises an alkenyl aromatic monomer and a capped poly(arylene ether),the composition may be prepared directly from an unfunctionalizedpoly(arylene ether) by dissolving the uncapped poly(arylene ether) in aportion of the alkenyl aromatic monomer, adding a capping agent to formthe capped poly(arylene ether) in the presence of the alkenyl aromaticmonomer, and adding the acryloyl monomer, the phosphorus flameretardant, and any other components to form the thermoset composition.

There is no particular limitation on the method by which the compositionmay be cured. The composition may, for example, be cured thermally or byusing irradiation techniques, including radio frequency heating, UVirradiation and electron beam irradiation. When heat curing is used, thetemperature selected may be about 80° to about 300° C. The heatingperiod may be about 5 seconds to about 24 hours. Curing may be staged toproduce a partially cured and often tack-free resin, which then is fullycured by heating for longer periods or at higher temperatures.

One embodiment is a cured composition obtained by curing any of theabove-described curable compositions. It will be understood that theterm “curing” includes partially curing and fully curing. Because thecomponents of the curable composition may react with each other duringcuring, the cured compositions may be described as comprising thereaction products of the curable composition components.

Another embodiment is an article comprising any of the curedcompositions. The curable composition is useful for fabricating a widerange of articles, and it is particularly suitable for use as anencapsulant for electronic devices. The composition exhibits highlydesirable properties. For example, in one embodiment, the curedcomposition may exhibit a UL94 flammability rating of V-1, preferably,V-0, at a thickness of 1 to 10 millimeters. The cured composition mayexhibit a glass transition temperature of at least 120° C., preferablyat least 130° C., more preferably at least 140° C. The cured compositionalso exhibits low moisture absorption that is highly reversible. Thecured composition dried for 24 hours at 115° C. exhibits a weightdifference less than ±0.05%, preferably less than ±0.02%, morepreferably less than ±0.01%, after exposure to 168 hours at 85° C. and85% relative humidity and redrying for 24 hours at 115° C. By less than±0.05%, it is meant that the absolute value of the weight change is lessthan 0.05%.

The invention is further illustrated by the following non-limitingexamples.

EXAMPLES 1 AND 2, COMPARATIVE EXAMPLES 1-3

Several compositions were prepared and molded using the components andamounts summarized in Table 1, where all amounts are expressed as partsby weight (pbw). A methacrylate-capped poly(2,6-dimethyl-1,4-phenyleneether) resin (“Methacrylate-capped PPE”) having an intrinsic viscosityof about 0.3 deciliters per gram was prepared according to proceduresdescribed in U.S. Patent Application Publication No. 2001/0053820 A1 toYeager et al. Fused silicas were obtained from Denka as FB-74 having anaverage particle size of 30.4 micrometers and a surface area of 1.6meter²/gram, and FS-20 having an average particle size of 5.0micrometers and a surface area of 6.7 meter²/gram. Hexanediol diacrylatewas obtained from Sartomer as SR238. Trimethylolpropane trimethacrylate(TMPTMA) was obtained from Sartomer as SR350. Methacryloxypropyltrimethoxysilane (MAPTMS) was obtained from Dow Corning as Z-6030. Aconductive carbon black was obtained as Printex XE-2 from Degussa.Triphenyl phosphate was obtained from Akzo Nobel. Piperazinebis(di-(2,6-dimethylphenyl)phosphoramidate) (sometimes referred to aspiperazine diphosphonate ester) was prepared by the reaction of2,6-dimethylphenol (GE Plastics) with phosphorus oxychloride in thepresence of magnesium chloride to give xylyl dichlorophosphate, whichwas further reacted in methylene chloride solvent with piperazine(Aldrich) in the presence of triethylamine (Aldrich) to give the desiredproduct. Aluminum tris(diethylphosphinate) was obtained as OP930 fromClariant. A dried colloidal powder of antimony pentoxide was obtainedfrom Nyacol as Nyacol A1590.

Molding compounds were prepared as follows. The fused silicas werecombined with the MAPTMS in a plastic container. The container was thenplaced into a two-axis, centrifugal mixer and allowed to mix for 15seconds at 1400 rpm. The container was then allowed to stand and coolfor 5 minutes. After cooling, the methacrylate-cappedpoly(2,6-dimethyl-1,4-phenylene ether) was added to the container, whichwas again placed in the centrifugal mixer and allowed to mix for 15seconds at 1400 rpm, allowed to stand and cool for 1 minute, and thenmixed again for 15 seconds at 1400 rpm. The remaining components of theformulation were then added and the resulting mixture was gently foldedtogether with a spatula. After folding, the mixture was again placed inthe centrifugal mixer and allowed to mix for 15 second at 1400 rpm.After the compound was allowed to cool, it was placed in a two-roll millfor further mixing. The mill utilized a chilled roll (35° C.) and a hotroll (50-70° C.) and ran at a speed of about 8-16 meters/minute and rollratio of 1:1-2:1. The gap in the nip was set initially at 0.5millimeters and was decreased to 0.25 millimeters as mixing progressed.The molding compound was allowed to mix on the two-roll mill for 6-10minutes, during which the compound was cut from the roll 10 times. Aftermixing was complete, the compound was cut from the two-roll mill andplaced in a sealed jar for storage in a freezer.

Test samples (“coupons”) were prepared from the molding compound byfirst compression molding the material into 3.175 millimeter thickdisks, and then cutting the disks into the appropriately sized bars fortesting. Compression molding of the molding compound was performed at150° C. under a pressure of 4.82-6.89 megapascals. A cure time of 5minutes was sufficient for the 3.175 millimeter thick part. Aftercompression molding, the plaques were post-cured in a circulating airoven at 175° C. for 1 hour. After post-curing the 3.175 millimeter thickplaques were cut into 1.27 centimeter wide strips using adiamond-wheeled wet saw of the kind typically used for cutting ceramicfloor tile. The 1.27 centimeter wide by 3.175 millimeter thick stripswere then cut to length for testing. After cutting was completed, thecoupons were washed thoroughly with isopropyl alcohol and dried in anopen-air oven for one to two hours at 110° C. Coupons used for moisturegain testing were then sanded smooth on their cut edges using 180, 220,and then 400 grit sandpaper. The molded surfaces were not sanded. Aftersanding was completed, the coupons were again cleaned in isopropylalcohol and again dried in an open-air oven at 110° C. for 2 hours.

Flammability testing was conducted according to Underwriter's Laboratoryprocedure UL94 using samples 3.175 millimeters (one-eighth inch) thickand 12.7 millimeters (one-half inch) wide. Glass transition temperatures(T_(g)) and coefficients of thermal expansion (CTE) were determined bythermal mechanical analysis according to ASTM D6341. CTE values areexpressed in units of parts per million (ppm), which are equivalent tomicrometers/meter/° C. Thermal Mechanical Analysis (TMA) was performedon a TA 2950 TMA Thermo Mechanical Analyzer. Experimental parameterswere set at: 0.05 Newton of force, nitrogen purge, and 1.0 sec/pointsampling interval. The sample temperature was ramped at 5° C./min from25° C. to 250° C. then cooled at 10° C./min to 0° C. The second heatramped from 0° C. at 5° C./min to 250° C. Data was reported from thesecond heat. CTE values were measured both above and below the glasstransition temperature.

Moisture absorption of the materials was determined by measuring theweight of a given coupon before and after conditioning in a controlledhumidity chamber. Prior to conditioning the coupons were cut to thedimensions of 6.35×1.27×0.3175 centimeters, dried for 1 hour at 115° C.,and then weighed to the nearest 0.0001 gram. After conditioning for 168hours, at 85° C. and 85% relative humidity, the coupons were immediatelyweighed and then allowed to dry overnight at ambient conditions.Following the overnight dry, the coupons were placed in an open-air ovenfor 2 hours at 115° C. and then immediately weighed. Weight changes areexpressed in Table 1 as a percentage relative to the pre-weighed value.

All property results are summarized in Table 1. The UL94 flammabilityresults show that the phosphorus flame retardant is more effective, on aweight basis, than either triphenyl phosphate or the piperazinephosphate compound. Only the compositions with the phosphorus flameretardant achieved the highly desirable V-0 rating. The results alsoshow that the compositions with phosphorus flame retardant closelyapproach their initial weight after exposure to high humidity followedby re-drying. In contrast, the compositions with triphenyl phosphatelost weight, possibly because of volatilization of the triphenylphosphate, and the composition with the piperazine phosphate gainedweight, possibly because of irreversible water absorption. TABLE 1 Ex. 1Ex. 2 C. Ex. 1 C. Ex. 2 C. Ex. 3 Composition Fused silica FB-74 66.4066.40 66.40 66.40 66.40 Fused silica FS-20 16.60 16.60 16.60 16.60 16.60Methacrylate-capped PPE 4.25 4.10 3.97 4.25 4.10 Dicumyl peroxide 0.320.32 0.32 0.32 0.32 Carbon black 0.20 0.20 0.20 0.20 0.20 4-t-Butylcatechol 0.04 0.04 0.04 0.04 0.04 Hexanediol diacrylate 7.89 7.62 7.377.89 7.62 TMPTMA 2.20 2.12 2.05 2.20 2.12 MAPTMS 0.50 0.50 0.50 0.500.50 Aluminum tris(diethylphosphinate) 1.60 2.10 0 0 0 Piperazinediphosphonate ester 0 0 2.55 0 0 Triphenyl phosphate 0 0 0 1.60 2.10Properties Total burn time for 5 samples (sec) 17.5 2.4 37.1 271.4 78.3Average burn time per sample (sec) 3.5 0.5 15.1 54.3 15.7 ContinuousBurn? no no no yes no Drip? no no no no no UL 94 rating V-0 V-0 V-1 noranking no ranking T_(g) (° C.) 144 144 110 101 89 CTE < T_(g) (ppm) 1412 15 16 18 CTE > T_(g) (ppm) 22 22 22 19 12 weight change after 168hours at +0.200 ± 0.004 +0.211 ± 0.002 +0.194 ± 0.006 +0.156 ± 0.012+0.091 ± 0.042 85° C./85% RH (%) weight change after redrying (%) +0.002± 0.004 −0.007 ± 0.003 +0.066 ± 0.008 −0.011 ± 0.008 −0.053 ± 0.004

EXAMPLES 3-11

A composition was prepared and molded according to the proceduredescribed above. Cyclohexanedimethanol diacrylate was obtained fromSartomer as CD 406. A partially calcium saponified glycolic ester ofmontanic acid (montan wax) in a micronized form was obtained asCERIDUST® 5551 from Clariant. A fused silica having a median particlesize of 17.7 micrometers and a surface area of 3.1 meter²/gram wasobtained as FB-570 from Denka. Another fused silica having a medianparticle size of 0.7 micrometers and a surface area of 6.2 meter²/gramwas obtained as SFP-30M from Denka. A colorant blend consisted of 57parts of red colorant obtained as SANDOPLAST® Red G and 43 parts ofgreen colorant obtained as SANDOPLAST® Green GSB, both from Clariant.Compositions are summarized in Table 2. Spiral flow length wasdetermined using a spiral flow mold with a channel depth of 0.762millimeters and a Gluco molding machine. Conditions used for themeasurements were: platen temperature, 165° C.; mold temperature, 150°C.; injection pressure, 6.89 megapascals; injection speed and timevaried with the composition, but an injection speed of about 7.62centimeters/second was typical, as was an injection time of about 6seconds; cycle time, 180 seconds. The composition may be ground to a drypowder, or converted to a hard pellet. Shore D hardness of pellets wasmeasured according to ASTM D2240. A qualitative friability test wasconducted by grinding the composition using a mortar and pestle, andsieving the resulting powder to a maximum particle size of 600micrometers. A composition was judged to be friable if the compositionwas easily ground into a dry powder and the powder did not self-sinterafter 24 hours storage at room temperature (i.e., it remained a finelyground powder). Properties are summarized in Table 2. The results showthat the compositions exhibit high spiral flow, and that they aresuitable for handling as either pellets or powders. TABLE 2 Ex. 3 Ex. 4Ex. 5 Ex. 6 Ex. 7 Ex. 8 Ex. 9 Ex. 10 Ex. 11 CompositionMethacrylate-capped PPE, IV = 0.12 13.18 0 25.28 22.12 18.96 15.80 12.640 6.32 Methacrylate-capped PPE, IV = 0.30 0 13.18 0 0 0 0 0 9.48 6.32Cyclohexanedimethanol diacrylate 52.71 52.71 37.91 41.07 44.23 47.3950.55 53.71 50.55 Montan wax 0 0 2.7 2.7 2.7 2.7 2.7 2.7 2.7 Dicumylperoxide 2.15 2.15 2.15 2.15 2.15 2.15 2.15 2.15 2.15 4-t-Butyl catechol0.13 0.13 0.13 0.13 0.13 0.13 0.13 0.13 0.13 Aluminumtris(diethylphosphinate) 7.56 7.56 7.56 7.56 7.56 7.56 7.56 7.56 7.56Fused silica FB-570 417.474 417.474 417.474 417.474 417.474 417.474417.474 417.474 417.474 Fused silica SFP-30 M 46.386 46.386 46.38646.386 46.386 46.386 46.386 46.386 46.386 Colorant 0.54 0.54 0.54 0.540.54 0.54 0.54 0.54 0.54 Properties Spiral Flow (meters) 1.54 0.27 0.420.53 0.61 0.66 0.90 — 0.46 Pellet Hardness (Shore D durometer) 44 — 5555 55 — — — — Friable? yes yes yes yes yes yes yes — yes

EXAMPLES 12-17, COMPARATIVE EXAMPLES 4-6

Seven compositions varying primarily in flame retardant type and amountwere compounded, molded, and tested for flammability according toUnderwriter's Laboratory procedure UL94. All samples contained silica, acolorant (carbon black or Keystone Green dye), a mold release agent(LICOWAX® S or LICOWAX® OP from Clariant), a flame retardant (melaminepolyphosphate obtained from Ciba as MELAPUR® 200, aluminum tris(diethylphosphinate) obtained from Clariant as OP930, or Clariant OP1311, whichis believed to be a 9:1 weight/weight mixture of aluminum tris(diethylphosphinate) and melamine polyphosphate), an initiator (dicumyl peroxideor t-butylperoxy benzoate), t-butylcatechol inhibitor, an acryloylmonomer (ethoxylated bisphenol A dimethacrylate obtained from Sartomeras SR348; 4-biphenyl methacrylate, CAS Reg. No. 46904-74-9, obtainedfrom Hampford Research; or 4,4′-biphenol dimethacrylate, CAS Reg. No.13082-48-9, prepared according to Liu et al., Polymer Preprints(American Chemical Society, Division of Polymer Chemistry) (2002),43(2), 1067), a functionalized poly(arylene ether) (methacrylatemonocapped poly(2,6-dimethyl-1,4-phenylene ether) having an intrinsicviscosity of about 0.3 dL/g or methacrylate dicappedpoly(2,6-dimethyl-1,4-phenylene ether) having an intrinsic viscosity ofabout 0.12 dL/g). Some samples included a styrene-maleic anhydridecopolymer. Compositions and flammability test results are presented inTable 3. The quantity “total burn time for 5 samples (sec)” representsthe total of first and second burn times for five samples of eachcomposition. A composition was deemed to have passed the UL94 V-0 testif it exhibited a total burn time less than 50 seconds with noindividual sample having a burn time greater than 10 seconds. Theresults, presented in Table 3, show that the aluminum tris(diethylphosphinate) and melamine polyphosphate are individually effective asflame retardants, and that their combination is synergisticallyeffective. TABLE 3 Ex. 12 Ex. 13 Ex. 14 Ex. 15 C. Ex. 4 C. Ex. 5 C. Ex.6 Ex. 16 Ex. 17 Silane-treated silica 85.60  85.60  85.60  85.60  85.60 85.60  85.60  85.00  85.47% Fumed silica — — — — — — — 0.50 — KeystoneGreen pigment 0.20 0.20 0.20 0.20 0.20 0.20 0.20 — — Carbon black — — —— — — — 0.36 0.20 Licowax OP 0.40 0.40 0.40 0.40 0.40 0.40 0.40 0.30 —Licowax S — — — — — — — — 0.20 Melamine polyphosphate — — — — 2.85 3.003.45 — — OP1311 1.66 1.40 1.20 — — — — 1.25 1.25 Aluminum tris(diethylphosphinate) — — — 1.40 — — — — — Dicumyl peroxide 0.36 0.36 0.36 0.360.36 0.36 0.36 — — t-Butyl peroxybenzoate — — — — — — — 0.36 0.38t-Butylcatechol 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.06 Ethoxylatedbisphenol A dimethacrylate 9.96 10.18  10.35  10.18  8.95 8.82 8.44 2.752.95 4-biphenyl methacrylate — — — — — — — 2.75 2.95 4,4′-biphenoldimethacrylate — — — — — — — 3.67 3.94 PPE monomethacrylate, 0.30 IV1.76 1.80 1.83 1.80 1.58 1.56 1.49 — — PPE dimethacrylate, 0.12 IV — — —— — — — 2.18 1.74 Styrene-maleic anhydride copolymer — — — — — — — 0.820.86 Total burn time for 5 samples (sec) 6.1  20.4  29.7  35.9  219.8  302.7   16.7  13.1  11.0  pass UL 94 V-0? yes yes yes yes no no yes yesyes

While the invention has been described with reference to a preferredembodiment, it will be understood by those skilled in the art thatvarious changes may be made and equivalents may be substituted forelements thereof without departing from the scope of the invention. Inaddition, many modifications may be made to adapt a particular situationor material to the teachings of the invention without departing from theessential scope thereof. Therefore, it is intended that the inventionnot be limited to the particular embodiment disclosed as the best modecontemplated for carrying out this invention, but that the inventionwill include all embodiments falling within the scope of the appendedclaims.

All cited patents, patent applications, and other references areincorporated herein by reference in their entirety.

1. A curable composition, comprising: a functionalized poly(aryleneether) resin; an acryloyl monomer; and a phosphorus flame retardanthaving the formula

wherein M^(d+) is a metal ion or an onium ion; d is 1, 2, 3, or 4according to the identity of M and its oxidation state; each occurrenceof R²³ and R²⁴ is independently C₁-C₁₈ hydrocarbyl; and each occurrenceof m and n is 0 or
 1. 2. The composition of claim 1, wherein thefunctionalized poly(arylene ether) resin is a capped poly(arylene ether)resin having the formulaQ(J-K)_(y) wherein Q is the residuum of a monohydric, dihydric, orpolyhydric phenol; y is 1 to 100; J comprises repeating structural unitshaving the formula

wherein R¹ and R³ are each independently selected from the groupconsisting of hydrogen, halogen, primary or secondary C₁-C₁₂ alkyl,C₂-C₁₂ alkenyl, C₂-C₁₂ alkynyl, C₁-C₁₂ aminoalkyl, C₁-C₁₂ hydroxyalkyl,phenyl, C₁-C₁₂ haloalkyl, C₁-C₁₂ hydrocarbyloxy, and C₂-C₁₂halohydrocarbyloxy wherein at least two carbon atoms separate thehalogen and oxygen atoms; R² and R⁴ are each independently selected fromthe group consisting of halogen, primary or secondary C₁-C₁₂ alkyl,C₂-C₁₂ alkenyl, C₂-C₁₂ alkynyl, C₁-C₁₂ aminoalkyl, C₁-C₁₂ hydroxyalkyl,phenyl, C₁-C₁₂ haloalkyl, C₁-C₁₂ hydrocarbyloxy, and C₂-C₁₂halohydrocarbyloxy wherein at least two carbon atoms separate thehalogen and oxygen atoms; m is 1 to about 200; and K is a capping groupselected from the group consisting of

wherein R⁵ is C₁-C₁₂ alkyl; R⁶-R⁸ are each independently selected fromthe group consisting of hydrogen, C₁-C₁₈ hydrocarbyl, C₂-C₁₈hydrocarbyloxycarbonyl, nitrile, formyl, carboxylate, imidate, andthiocarboxylate; R⁹-R¹³ are each independently selected from the groupconsisting of hydrogen, halogen, C₁-C₁₂ alkyl, hydroxy, and amino; andwherein Y is a divalent group selected from the group consisting of

wherein R¹⁴ and R¹⁵ are each independently selected from the groupconsisting of hydrogen and C₁-C₁₂ alkyl.
 3. The curable composition ofclaim 2, wherein Q is the residuum of a monohydric phenol.
 4. Thecurable composition of claim 1, wherein the capped poly(arylene ether)comprises at least one capping group having the structure

wherein R⁶-R⁸ are each independently selected from the group consistingof hydrogen, C₁-C₁₈ hydrocarbyl, C₂-C₁₂ hydrocarbyloxycarbonyl, nitrile,formyl, carboxylate, imidate, and thiocarboxylate.
 5. The curablecomposition of claim 4, wherein R⁶ is hydrogen or methyl, and R⁷ and R⁸are hydrogen.
 6. The curable composition of claim 1, comprising about 5to about 90 parts by weight of the functionalized poly(arylene ether)per 100 parts by weight total of the functionalized poly(arylene ether)and the acryloyl monomer.
 7. The composition of claim 1, wherein theacryloyl monomer comprises at least one acryloyl moiety having thestructure

wherein R¹⁸ and R¹⁹ are each independently selected from the groupconsisting of hydrogen and C₁-C₁₂ alkyl, and wherein R¹⁸ and R¹⁹ may bedisposed either cis or trans about the carbon-carbon double bond.
 8. Thecomposition of claim 1, wherein the acryloyl monomer comprises at leastone acryloyl moiety having the structure

wherein R²⁰-R²² are each independently selected from the groupconsisting of hydrogen, C₁-C₁₂ hydrocarbyl, C₂-C₁₈hydrocarbyloxycarbonyl, nitrile, formyl, carboxylate, imidate, andthiocarboxylate.
 9. The composition of claim 8, wherein the acryloylmonomer comprises at least two acryloyl moieties.
 10. The composition ofclaim 8, wherein the acryloyl monomer comprises at least three acryloylmoieties.
 11. The composition of claim 1, wherein the acryloyl monomeris selected from trimethylolpropane tri(meth)acrylate, 1,6-hexanedioldi(meth)acrylate, neopentyl glycol di(meth)acrylate, ethylene glycoldi(meth)acrylate, propylene glycol di(meth)acrylate,cyclohexanedimethanol di(meth)acrylate, butanediol di(meth)acrylate,diethylene glycol di(meth)acrylate, triethylene glycol di(meth)acrylate,isobornyl (meth)acrylate, methyl (meth)acrylate, methacryloxypropyltrimethoxysilane, ethoxylated (2) bisphenol A di(meth)acrylate,4-biphenyl (meth)acrylate, 4,4′-biphenol di(meth)acrylate, and mixturesthereof.
 12. The composition of claim 1, comprising about 10 to about 95parts acryloyl monomer per 100 parts by weight total of thefunctionalized poly(arylene ether) and the acryloyl monomer.
 13. Thecomposition of claim 1, wherein each occurrence of R²³ and R²⁴ isindependently C₁-C₆ alkyl.
 14. The composition of claim 1, wherein eachoccurrence of R²³ and R²⁴ is methyl or ethyl.
 15. The composition ofclaim 1, wherein M is aluminum and each occurrence of m and n is zero.16. The composition of claim 1, wherein the phosphorus flame retardantis aluminum tris(diethylphosphinate).
 17. The composition of claim 1,comprising about 0.1 to about 50 parts by weight of the phosphorus flameretardant per 100 parts by weight total of the functionalizedpoly(arylene ether) and the acryloyl monomer.
 18. The composition ofclaim 1, further comprising an aromatic bisphosphoramidate flameretardant of the formula

wherein A is a monocyclic aromatic radical and D¹ is a C₁₋₄ primary orsecondary alkyl radical or both D¹ radicals taken together are ethylene.19. The composition of claim 1, further comprising an aromaticpolyphosphate flame retardant having the formula

wherein each occurrence of R⁶-R⁸ is independently selected from thegroup consisting of hydrogen, C₁-C₁₈ hydrocarbyl, C₂-C₁₂hydrocarbyloxycarbonyl, nitrile, formyl, carboxylate, imidate, andthiocarboxylate; r is 2 to about 20; and each occurrence of s is 0, 1,or 2, with the proviso that at least one occurrence of s is
 1. 20. Thecurable composition of claim 1, further comprising a nitrogen-containingflame retardant selected from triazines, guanidines, cyanurates,isocyanurates, ammonium polyphosphates, and mixtures thereof.
 21. Thecurable composition of claim 20, wherein the nitrogen-containing flameretardant comprises a melamine polyphosphate represented by the formula

wherein g has an average value of about 3 to about 10,000, and the ratioof f to g is about 0.5:1 to about 1.7:1.
 22. The composition of claim 1,further comprising an alkenyl aromatic compound having the formula

wherein each occurrence of R¹⁶ is independently hydrogen or C₁-C₁₈hydrocarbyl; each occurrence of R¹⁷ is independently halogen, C₁-C₁₂alkyl, C₁-C₁₂ alkoxyl, or C₆-C₁₈ aryl; p is 1 to 4; and q is 0 to
 5. 23.The curable composition of claim 22, wherein the alkenyl aromaticmonomer is selected from styrene, α-methylstyrene, 2-methylstyrene,3-methylstyrene, 4-methylstyrene, 2-t-butylstyrene, 3-t-butylstyrene,4-t-butylstyrene, 1,3-divinylbenzene, 1,4-divinylbenzene,1,3-diisopropenylbenzene, 1,4-diisopropenylbenzene, styrenes having from1 to 5 halogen substituents on the aromatic ring, and combinationsthereof.
 24. The composition of claim 22, comprising about 10 to about500 parts by weight alkenyl aromatic monomer per 100 parts by weighttotal of the functionalized poly(arylene ether) and the acryloylmonomer.
 25. The composition of claim 1, further comprising an allylicmonomer.
 26. The composition of claim 25, wherein the allylic monomer isselected from diallyl phthalate, diallyl isophthalate, triallylmellitate, triallyl mesate, triallyl benzenes, triallyl cyanurate,triallyl isocyanurate, and mixtures thereof.
 27. The composition ofclaim 25, comprising about 10 to about 500 parts by weight allylicmonomer per 100 parts by weight total of the functionalized poly(aryleneether) and the acryloyl monomer.
 28. The curable composition of claim 1,further comprising about 5 to about 95 weight percent of a particulatefiller, based on the total weight of the composition.
 29. The curablecomposition of claim 28, wherein the particulate filler is fused silica.30. The curable composition of claim 28, wherein the particulate fillercomprises a first fused silica having an average particle size of about0.03 micrometer to less than 1 micrometer, and a second fused silicahaving an average particle size greater than 1 micrometer to about 30micrometers.
 31. The curable composition of claim 1, further comprisinga curing catalyst.
 32. The curable composition of claim 31, wherein thecuring catalyst is selected from benzoyl peroxide, dicumyl peroxide,methyl ethyl ketone peroxide, lauryl peroxide, cyclohexanone peroxide,t-butyl hydroperoxide, t-butyl benzene hydroperoxide, t-butylperoctoate, 2,5-dimethylhexane-2,5-dihydroperoxide,2,5-dimethyl-2,5-di(t-butylperoxy)-hex-3-yne, di-t-butylperoxide,t-butylcumyl peroxide, α,α′-bis(t-butylperoxy-m-isopropyl)benzene,2,5-dimethyl-2,5-di(t-butylperoxy)hexane, di(t-butylperoxy)isophthalate, t-butylperoxybenzoate, 2,2-bis(t-butylperoxy)butane,2,2-bis(t-butylperoxy)octane, 2,5-dimethyl-2,5-di(benzoylperoxy)hexane,di(trimethylsilyl)peroxide, trimethylsilylphenyltriphenylsilyl peroxide,and mixtures thereof.
 33. The curable composition of claim 1, furthercomprising a curing inhibitor.
 34. The curable composition of claim 33,wherein the curing inhibitor is selected from diazoaminobenzene,phenylacetylene, sym-trinitrobenzene, p-benzoquinone, acetaldehyde,aniline condensates, N,N′-dibutyl-o-phenylenediamine,N-butyl-p-aminophenol, 2,4,6-triphenylphenoxyl, pyrogallol, catechol,hydroquinone, C₁-C₆-alkyl-substituted catechols, dialkylhydroquinone,2,4,6-dichloronitrophenol, halogen-ortho-nitrophenols,alkoxyhydroquinone, mono- and di- and polysulfides of phenols andcatechols, thiols and oximes and hydrazones of quinone, phenothiazine,dialkylhydroxylamines, and combinations thereof.
 35. The curablecomposition of claim 1, further comprising an additive selected fromdyes, pigments, colorants, antioxidants, heat stabilizers, lightstabilizers, plasticizers, lubricants, flow modifiers, drip retardants,flame retardants, antiblocking agents, antistatic agents, flow-promotingagents, processing aids, substrate adhesion agents, mold release agents,toughening agents, low-profile additives, stress-relief additives, andcombinations thereof.
 36. A curable composition, comprising: a(meth)acrylate-capped poly(2,6-dimethyl-1,4-phenylene ether) resin, a(meth)acrylate-capped poly(2,6-dimethyl-1,4-phenyleneether-co-2,3,6-trimethyl-1,4-phenylene ether) resin, or a mixturethereof; an acryloyl monomer selected from trimethylolpropanetri(meth)acrylate, hexanediol di(meth)acrylate, cyclohexanedimethanoldi(meth)acrylate, methacryloxypropyl trimethoxysilane, ethoxylated (2)bisphenol A dimethacrylate, 4-biphenyl (meth)acrylate, 4,4′-biphenoldi(meth)acrylate, and mixtures thereof; an aluminophosphorus flameretardant having the formula

wherein each occurrence of R²³ and R²⁴ is independently C₁-C₆ alkyl, andeach occurrence of m and n is 0; a melamine polyphosphate represented bythe formula

wherein g has an average value of about 3 to about 10,000, and the ratioof f to g is about 0.5:1 to about 1.7:1; and fused silica.
 37. A curedcomposition, comprising the reaction product obtained by curing thecurable composition of claim
 36. 38. A curable composition, comprising:about 5 to about 40 parts by weight of a (meth)acrylate-cappedpoly(2,6-dimethyl-1,4-phenylene ether) resin, a (meth)acrylate-cappedpoly(2,6-dimethyl-1,4-phenylene ether-co-2,3,6-trimethyl-1,4-phenyleneether) resin, or a mixture thereof; about 60 to about 95 parts by weightof an acryloyl monomer selected from trimethylolpropanetri(meth)acrylate, hexanediol di(meth)acrylate, cyclohexanedimethanoldi(meth)acrylate, methacryloxypropyl trimethoxysilane, ethoxylated (2)bisphenol A di(meth)acrylate, 4-biphenyl (meth)acrylate, 4,4′-biphenoldi(meth)acrylate, and mixtures thereof; about 1 to about 50 parts byweight of aluminum tris(diethylphosphinate); and about 0.1 to about 5parts by weight of a melamine polyphosphate; about 100 to about 2,000parts by weight of fused silica; wherein all parts by weight are basedon 100 parts by weight total for the (meth)acrylate-capped poly(aryleneether) resin and the acryloyl monomer.
 39. A cured composition,comprising the reaction product obtained by curing the curablecomposition of claim
 38. 40. A cured composition, comprising thereaction product obtained by curing the curable composition of claim 1.41. The cured composition of claim 40, having a UL94 rating of V-0 orV-1 at a thickness of 1 to 10 millimeters.
 42. The cured composition ofclaim 40, having a glass transition temperature of at least 120° C. 43.The cured composition of claim 40, wherein the composition dried for 24hours at 115° C. exhibits a weight difference less than ±0.05% afterexposure to 168 hours at 85° C. and 85% relative humidity and redryingfor 24 hours at 115° C.
 44. An article comprising the cured compositionof claim
 37. 45. An article comprising the cured composition of claim39.
 46. An article comprising the cured composition of claim
 40. 47. Amethod of preparing a curable composition, comprising: blending afunctionalized poly(arylene ether) resin; an acryloyl monomer; and aphosphorus flame retardant having the formula

wherein M^(d+) is a metal ion or an onium ion; d is 1, 2, 3, or 4according to the identity of M and its oxidation state; each occurrenceof R²³ and R²⁴ is independently C₁-C₁₈ hydrocarbyl; and each occurrenceof m and n is 0 or 11 to form an intimate blend.